Angelina Jolie meets with UN Secretary General António Guterres in NYC

Following the Toronto Film Festival premiere of her fifth directorial effort, Angelina Jolie met with United Nations Secretary General António Guterres at the Manhattan headquarters on Thursday, the Daily Mail reports.

The Special Envoy for the UN High Commissioner for Refugees easily defied her 41 years in a white silk blouse, brown pencil skirt, and nude pumps selected by stylist Jen Rade.

Hairstylist Adam Campbell blew out the Oscar winner's naturally brunette locks and she finished off her business attire with diamond earring and a crimson pout and manicure.

Rather than taking vacuous selfies or developing clothing lines, Angelina has made over 60 trips to the field as part of her work with the do-gooding intergovernmental organization.

On Wednesday, Jolie gave an update on her tough divorce from estranged third husband Brad Pitt after 12 years together.  

“None of it's easy. It's very, very difficult, a very painful situation, and I just want my family healthy,” the By the Sea director admitted to the New York Times.

“They're getting better.”  

The former Hollywood wild child's big blended brood - including Zahara, 12; Shiloh, 11; and twins Vivienne & Knox, 9 - attended the TIFF premiere of First They Killed My Father on Monday.

It currently holds a 76 percent critic approval rating on Rotten Tomatoes, a 70 percent approval rating on MetaCritic, and a 6.7/10 on IMDb.